The Municipality of Sta Catalina is divided into 22 Barangays, which is led and governed by Punong Barangay (barangay captain) and officials.
+ Alangilan ---- JUANITO F. BUNGCASAN
+ Amio --- JESUSA O. GENIL
+ Buenavista --- NICASIO C. GAUDIA
+ Kabulacan --- JOVENCIANO M. GEROMO
+ Caigangan --- JESSIE T. CADIS
+ Caranoche --- ALFONSO E. OLAM
+ Cawitan --- EDUARDO V. ALILING
+ Fatima --- JURRY M. LAGUARDIA
+ Mabuhay --- JOSELITO P. NAMOCO
+ Manalongon --- ELEGIO N. MONTE DE RAMOS
+ Mansagomayon --- EDWIN S. ESPARCIA
+ Milagrosa --- CONSTANTINO B. VILLANUEVA
+ Nagbinlod --- ROSENDA P. TRAÑA
+ Nagbalaye --- MARLOU E. AGBON
+ Obat --- JONATHAN S. ESTRELLANES
+ Poblacion --- ANTERO T. BIGAY
+ San Francisco --- FLORITA L. ACSON
+ San Jose --- LOYOLO P. LALAMONAN
+ San Miguel --- REYNANTE S. MAGLANGIT
+ San Pedro --- RUEL M. BADON
+ Santo Rosario --- CRESENCIA H. NUICO
+ Talalak --- GLICERIO T. BIGAY
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A barangay is led and governed by its barangay officials. The "barangay officials" is considered as a Local Government Unit (LGU) same as the Provincial and the Municipal Government. It is composed of a Punong Barangay, seven (7) Barangay Counselors or Barangay Kagawad, and a Sangguniang Kabataan (SK) Chairman which is considered as a member of the Council.